Methodology for classification of storage classes

  1. The hazardous substances can be divided into storage classes to allow the possibilities for joint storage to be determined. They are used exclusively for the management of joint storage.
  2. The definition of storage classes is primarily based on the classification according to Regulation (EC) No. 1272/2008 (CLP Regulation), the Hazardous Substances Ordinance, EC Directives 67/548/EEC and 1999/45/EC and the regulations for the carriage of dangerous goods. Further differentiations based on other legal provisions, the Technical Rules for Hazardous Substances (TRGS) and the general product properties are also taken into account.
  3. A hazardous substance is assigned to a storage class using the available information. Such information is derived, in particular, from details in the safety data sheet, the markings specific to the hazardous substance or the markings according to dangerous goods legislation. In the case of hazardous substances that are not marked as dangerous, information from the supplier or knowledge obtained from practical experience can be used.
  4. The classification guidance lists the hazard indicators from the marking that govern the classification of the storage class.
  5. Hazardous substances are grouped into a storage class if their hazard indicators are deemed to be similar and therefore necessitate similar protective measures.
  6. Each hazardous substance shall be classified into one storage class only.
  7. The storage class is determined by the first applicable hazard in the flow chart.
  8. During the transition period of the CLP Regulation, it is up to the warehouse keeper to decide whether to take account of the present labelling (hazard symbol and R-phrases) or the GHS labelling (pictogram and H-statements) when assigning the storage class.
  9. In cases of labelling under the dangerous goods legislation, both the primary hazard and the subsidiary hazards must be taken into account.
  10. For the purposes of joint storage, combustible substances are substances to which no physical danger is assigned under the CLP Regulation, but which experience has shown to be combustible or which have a flashpoint or an ignition temperature.
  11. Where fire barriers are formed with non-combustible substances/products during joint storage, these substances must be assigned to storage classes 12 or 13.

Description of the storage classes

Storage class 1: Explosive hazardous substances
Storage class 2A: Gases (except aerosol dispensers and lighters)
Storage class 2B: Aerosol dispensers and lighters
Storage class 3: Flammable liquids
Storage class 4.1A: Other potentially explosive hazardous substances
Storage class 4.1B: Flammable solids
Storage class 4.2A: Pyrophoric or self-heating substances
Storage class 4.3: Hazardous substances that release flammable gases when in contact with water
Storage class 5.1A: Highly oxidising substances
Storage class 5.1B: Oxidising substances
Storage class 5.1C: Ammonium nitrate and preparations containing ammonium nitrate
Storage class 5.2: Organic peroxides and self-reactive substances
Storage class 6.1A: Combustible substances of acute toxicity, categories 1 and 2/very toxic substances
Storage class 6.1B: Non-combustible substances of acute toxicity, categories 1 and 2/very toxic substances
Storage class 6.1C: Combustible substances of acute toxicity, category 3/hazardous substances
that are toxic or produce chronic effects
Storage class 6.1D: Non-combustible substances of acute toxicity, category 3/hazardous
substances that are toxic or produce chronic effects/td>
Storage class 6.2: Infectious substances
Storage class 7: Radioactive substances
Storage class 8A: Combustible corrosive substances
Storage class 8B: Non-combustible corrosive substances
Storage class 9: no classification
Storage class 10: Combustible liquids that cannot be assigned to any of the above classes
Storage class 11: Combustible solids that cannot be assigned to any of the above
storage classes
Storage class 12: Non-combustible liquids that cannot be assigned to any of the above
storage classes
Storage class 13: Non-combustible solids that cannot be assigned to any of the above
storage classes

Procedure for assigning storage classes






Additional information

(1) Self-reactive substances of hazard class 4.1 have properties comparable to those of the organic peroxides in storage class 4.1A or storage class 5.2 and must therefore likewise be assigned to these classes rather than to storage class 4.1B. Hazardous Substances of class 4.1 according to the dangerous goods legislation and which are not, for example, classified with R11 or H228 require a case-by-case analysis (for example sulphur, naphthalene, paraformaldehyde).

(2) Storage class 9 is empty.

(3) All liquids that are not assigned to one of the storage classes 1 to 8 are assigned to storage class 10 (flammable liquids).

(4) Storage class 11 (flammable solids) covers solids that experience has shown to be combustible. Combustibility may also be determined by the assignment of a combustion class of 2, 3, 4 or 5 (at room temperature) as defined in VDI 2263 Part 1.
Examples:
Combustion class 2: Tartaric acid
Combustion class 3: Lactose
Combustion class 4: Tobacco
Combustion class 5: Metamizole

(5) Storage class 12 (non-combustible liquids) includes:
1. liquid preparations containing ammonium nitrate in subgroups D I and D II of Annex I (5) to the Hazardous Goods Ordinance,
2. liquids that are not combustible or with a low ignition tendency

(6) Storage class 13 (non-combustible solids) includes solids that experience has shown not to be combustible and that do not meet the criteria of storage class 11. Combustion class 1 is assigned to substances such as table salt that do not burn in the determination according to VDI 2263 Part 1.

(7) Storage classes 10 to 13 primarily relate to liquids and solids that do not require labelling under the dangerous goods legislation. They may also cover hazardous substances that are marked with the hazard symbols Xn, harmful; Xi, irritant; or N, dangerous to the environment, as well as solids or liquids classified as class 9 according to the dangerous goods legislation. (

(8) The storage classes 10 to 13 can be summarised and then treated according to the joint-storage rules for storage class 11.

Joint Storage

Basic rules

(1) Hazardous substances may only be stored jointly if this does not increase the risk.

(2) In order to define the possibilities for joint storage, hazardous substances are assigned to storage classes in these technical rules. Their only purpose is to control the joint storage of substances. Storage classes must be defined according to the procedures stipulated in Annex 4.

(3) Separate storage means separating different stored substances in different warehouse areas of the same warehouse sector by sufficient distances or using barriers (e.g. walls, cabinets made of non-combustible materials, products made of non-combustible substances of storage class 12 or 13) or by storing them separately in structurally separate containment areas.

(4) Separate storage within one warehouse sector may be necessary in order to reduce hazards related to specific stored substances of the same storage class or substances of different storage classes. This can be achieved by sufficient distances or by barriers (e.g. walls, cabinets made of non-combustible materials, products made of non-combustible substances of storage class 12 or 13) or by storing them separately in separate containment areas. Indications for the need to store substances separately may result from, for example:
1. danger features and safety indicators that supplement the risk indicators (R- and S-phrases and/or H-, EUH- and P-sentences) of the marking (this applies in particular to R29, R31, R32, S14, S17, S50, EUH014, EUH029, EUH031, EUH032, P220, P223 and P420) and
2. product-related safety information, such as:
      a) safety data sheets (No. 5 Fire fighting measures and No. 7 Handling and Storage; less detailed are data in Safety Data Sheet No. 10 Stability and Reactivity) as experience has shown, or
      b) information leaflets issued by the accident insurance funds (example: cyanides shall not be stored jointly with substances – e.g. acids – with which they may produce hydrogen cyanide).

(5) Separate storage means storing substances separately in different warehouse sectors with a fire resistance rating or capability of at least 90 minutes. (

(6) Derogations from joint storage rules are allowed, provided that:
1. no more than 400 kg of hazardous substances are stored of which max. 200 kg may belong to one storage class,
2. hazardous substances of up to 200 kg are additionally stored in a warehouse for storage classes 6.1 C, 6.1 D, 8A, 8B and 10 to 13, and
3. there is no need to fear an increase in the risks encountered.

(7) Stored substances of different storage classes must not be stored in the same warehouse sector if the joint storage table pursuant to No. 7.2 prescribes separate storage in different warehouse sectors with a fire resistance rating or capability of at least 90 minutes (separate storage).

(8) Stored substances from the same storage class or stored substances from different storage classes for which no separate storage is prescribed, must also not be stored jointly if this can cause a substantial increase in risk. This is the case if they, for example:
1. require different extinguishing agents,
2. require different temperature conditions,
3. react with each other while producing flammable or toxic gases or
4. react with each other while causing a fire.

(9) In individual cases it is possible to deviate from the rules in the joint storage table on account of suitable fire protection concepts or risk assessment results.

(10) Exemptions from the rules for joint storage are permissible regarding the storage of hazardous substances in railway tank wagons certified according to dangerous goods rules or tanks on closed company premises if
1. this does not increase the risks,
2. the storage period does not exceed three months,
3. the transport containers are not opened during this time (they may be opened briefly solely for sampling purposes, taking account of the protective measures required for this activity), and
4. the transport containers are regularly, at least daily, inspected to see whether they are kept in good condition.

(11) Joint storage prohibitions shall not apply if packed hazardous substances are kept ready for transport in closed freight containers, e.g. in container berths and in container terminals, and if the closed freight containers are not stacked vertically or placed directly next to each other, and provided the rules for joint storage in the Dangerous Goods Ordinance Road, Railway and Inland Waterways are observed. This requirement shall be deemed to have been complied with if the minimum distance is 0.5 m in all directions.

Joint storage table

(1) The Joint Storage Table (Table 2) indicates for each storage class: whether joint storage with any of the other storage classes is allowed in principle; whether separate storage in different warehouse sectors with a fire resistance rating or capability of at least 90 minutes is present; or whether a restriction for joint storage must be observed (e.g. separate storage required in the event of storage in different warehouse areas in the same warehouse sector). (The Joint Storage Table also includes stored substances that do not come under the scope of application of these technical rules.)

(2) For the purpose of this joint-storage concept, combustible materials shall be stored substances to which no physical hazard is assigned pursuant to the CLP Regulation but that are known from experience to be combustible.

Table 2: Joint storage table according to storage class, explanations see subsequent pages
Storage class 10-13 13 12 11 10 8B 8A 7 6.2 6.1D 6.1C 6.1B 6.1A 5.2 5.1C 5.1B 5.1A 4.3 4.2 4.1B 4.1A 3 2B 2A 1
Explosive substance 1 1
Gases 2A 2 2 2 1 2 3
Aerosol packages 2B 1
Flammable liquids 3 5 5 6 4
Other explosive substances 4.1A 1 1 1 1 1 1 1 1 1 1
Flamable solid or desensitizing explosive substances 4.1B 6 4 1 4 6 6
Pyrophoric or self-igniting substances 4.2 6 6 6 6 6 6 6 6
Substances producing oxydizing gases with water 4.3 6 6 6 6 6 6 6 6
Highly oxydising substances 5.1A
Oxydizing substance 5.1B 7 7 7 7 6 6 4 4 1
Ammonium nitrate and mixtures containing ammonium nitrate 5.1C 1 1 1 1 1 1 1 1
organic peroxydes and self-reactive substances 5.2 1 1 1
Combustible, acutely toxic substance 6.1A 5 5
Non-combustible, acutely toxic substance 6.1B 5 5
Combustible, acutely toxic or chronic substance 6.1C
Non-combustible, acutely toxic substance or substances with chronic effects 6.1D
infectious substances 6.2
Radioactive substances 7 1
Combustible corrosive substances 8A
Non-combustible corrosive substances 8B
Combustible liquids 10
Combustible solids 11
Non-combustible liquids 12
Non-combustible solids 13
Other combustible and non-combustible substances 10-13

Separate storage is requires
Joint storage permitted
Number Joint storage is only permitted with restrictions (see Number)

Explanations with regard to Table 2

(1) Specific statutory storage rules must be observed

Storage class 1 and storage class 4.1.A 2. Explosion Ordinance (SprengV);
Storage class 5.1 C: Dangerous Substances Ordinance (GefStoffV) Annex III No. 5 Ammonium nitrate and TRGS 511;
Storage class 5.2 BGV B 4 “Organic peroxides”; attention: the joint storage rules quoted here shall also be applied by analogy to selfreactive hazardous substances;
Storage class 7 Radiation Protection Ordinance (StrlSchV) and DIN 25422.

(2) Joint storage in rooms is only allowed if:
1. max. 50 filled pressurised gas containers are stored, of which no more than 25 contain gases that are flammable, oxidising, acutely toxic, marked with H331 or toxic, and if these
2. are separated by a wall that is at least 2 m high and made of noncombustible materials and if
3. a distance of at least 5 m is observed between the wall and the combustible substances.

(3) Pressurised gas cylinders filled with different gases may only be jointly stored in the same warehouse room under the following conditions.
1. Pressurised gas containers containing gases that are flammable, oxidising, acutely toxic, marked with H331 or toxic, provided the total number of 150 pressurised gas containers or 15 pressure barrels is not exceeded. In addition, pressurised gas containers filled with inert gases may be stored in any quantity.
2. Pressurised gas containers with flammable and pressurised gas containers with inert gases may be stored in any quantity.
3. Pressurised gas containers with oxidising gases and pressurised gas containers with inert gases may be stored in any quantity.
4. Pressurised gas containers with acutely toxic hazardous substances of categories 1, 2 or 3/very toxic, toxic and pressurised gas containers with inert gases may be stored in any quantity.
5. In the cases 1 to 3, an additional 15 pressurised gas containers or a pressure barrel containing gases that are acutely toxic, marked with H330, and/or very toxic may be stored. Larger quantities of pressurised gas containers with acutely toxic gases must be stored in a special storage room.
6. There must be a distance of at least 2 m between pressurised gas containers containing flammable gases and pressurised gas containers containing oxidising gases. .
7. There are no restrictions as to outdoor storage.

(4) Joint storage shall be permitted if the restrictions of:
1. Table 3 are observed for storage classes 3, 5.1B, 6.1A and 6.1B,
2. Table 4 are observed for storage class 4.1B with storage class 6.1A.

Table 3: Preconditions for joint storage of storage classes 3, 5.1B, 6.1A and 6.1B
Total quantity Restrictions
up to 1 t without restrictions
up to 20 t in buildings if:
- an automatic fire extinguishing installation exists or
- an automatic fire detection system exists in combination with a non-automatic fire extinguishing installation and a certified plant fire brigade. /td>

Table 4: Preconditions for joint storage of storage class 4.1B with 6.1A
Total quantity Restrictions
up to 10 t without restrictions,
up to 20 t if
- in buildings: an automatic fire detection system exists,
- outdoors: fire detection and fire alarm are guaranteed by
      - hourly controls with alert possibilities (e.g. via telephone, fire alarm, radio equipment, etc.) or if
      - there is evidence that an appropriate automatic fire alarm/detection system exists.
up to 50 t if
- an automatic fire detection system exists and
- the fire brigade can reach the scene of the fire within 10 minutes of the alarm being raised.
up to 100 t if
- an automatic fire extinguishing installation exists or
- an automatic fire detection system exists in combination with a non-automatic fire extinguishing installation and a certified plant fire brigade.

(5) Materials that may contribute to the outbreak or rapid expansion of a fire due to their nature and quantity, as e.g. paper, textiles, wood, wood wool, hay, straw, packagings, combustible packaging filling materials, must not be stored in the warehouse sector unless they form a unit with the non-stationary containers for storage or transport.

(6) Different stored substances may only be stored together or jointly with other materials provided that this will not lead to a substantial increase in risk. A substantial increase in risk can be prevented through separate storage.

(7) Oxidising hazardous materials may be stored jointly with combustible materials:
1. in quantities of up to a total of 1 tonne without restrictions,
2. in quantities of more than 1 tonne according to the restrictions under explanation no. 1.
The requirements under explanation 5 must also be observed.

Back to
Joint Storage Table